UNITED STATES
SECURITIES AND EXCHANGE COMMISSION
Washington, DC 20549

FORM N-Q

QUARTERLY SCHEDULE OF PORTFOLIO HOLDINGS OF REGISTERED MANAGEMENT INVESTMENT COMPANY

Investment Company Act file number         811-7056         

        Nuveen Select Maturities Municipal Fund         
(Exact name of registrant as specified in charter)

Nuveen Investments
        333 West Wacker Drive, Chicago, Illinois 60606         
(Address of principal executive offices) (Zip code)

Kevin J. McCarthy Vice President and Secretary
        333 West Wacker Drive, Chicago, Illinois 60606         
(Name and address of agent for service)

Registrant's telephone number, including area code:         312-917-7700        

Date of fiscal year end:            3/31          

Date of reporting period:         6/30/09         

Form N-Q is to be used by management investment companies, other than small business investment companies registered on Form N-5 (§§ 239.24 and 274.5 of this chapter), to file reports with the Commission, not later than 60 days after the close of the first and third fiscal quarters, pursuant to rule 30b1-5 under the Investment Company Act of 1940 (17 CFR 270.30b1-5). The Commission may use the information provided on Form N-Q in its regulatory, disclosure review, inspection, and policymaking roles.

A registrant is required to disclose the information specified by Form N-Q, and the Commission will make this information public. A registrant is not required to respond to the collection of information contained in Form N-Q unless the Form displays a currently valid Office of Management and Budget ("OMB") control number. Please direct comments concerning the accuracy of the information collection burden estimate and any suggestions for reducing the burden to the Secretary, Securities and Exchange Commission, 450 Fifth Street, NW, Washington, DC 20549-0609. The OMB has reviewed this collection of information under the clearance requirements of 44 U.S.C. § 3507.

Item 1. Schedule of Investments

		Portfolio of Investments (Unaudited)
		Nuveen Select Maturities Municipal Fund (NIM)
		June 30, 2009
Principal				Optional Call
Amount (000)		Description (1)		Provisions (2)		Ratings (3)		Value
		Alabama – 2.3%
$ 2,000		Alabama 21st Century Authority, Tobacco Settlement Revenue Bonds, Series 2001, 5.750%, 12/01/17		12/11 at 101.00		A–	$	1,881,560
500		Jefferson County, Alabama, Sewer Revenue Refunding Warrants, Series 2003B, 5.250%, 2/01/12 –		2/10 at 100.00		AAA		458,515
		FSA Insured
500		Marshall County Healthcare Authority, Alabama, Revenue Bonds, Series 2002A, 6.250%, 1/01/22		1/12 at 101.00		A–		505,305
3,000		Total Alabama						2,845,380
		Arizona – 1.0%
80		Phoenix Industrial Development Authority, Arizona, Statewide Single Family Mortgage Revenue		9/09 at 100.50		AAA		80,272
		Bonds, Series 1998C, 6.650%, 10/01/29 (Alternative Minimum Tax)
		Salt Verde Financial Corporation, Arizona, Senior Gas Revenue Bonds, Series 2007:
100		5.000%, 12/01/17		No Opt. Call		A		88,640
85		5.250%, 12/01/19		No Opt. Call		A		74,907
35		5.000%, 12/01/32		No Opt. Call		A		26,601
380		5.000%, 12/01/37		No Opt. Call		A		283,427
750		Surprise Municipal Property Corporation, Arizona, Wastewater System Revenue Bonds, Series		4/11 at 100.00		N/R		651,000
		2007, 4.500%, 4/01/17
1,430		Total Arizona						1,204,847
		Arkansas – 4.2%
1,000		Fort Smith, Arkansas, Water and Sewer Revenue Refunding and Construction Bonds, Series 2002A,		10/11 at 100.00		AAA		1,094,540
		5.250%, 10/01/17 (Pre-refunded 10/01/11) – FSA Insured
1,500		Jefferson County, Arkansas, Pollution Control Revenue Bonds, Entergy Arkansas Inc. Project,		6/11 at 100.00		A–		1,479,645
		Series 2006, 4.600%, 10/01/17
1,000		Jonesboro, Arkansas, Industrial Development Revenue Bonds, Anheuser Busch Inc. Project, Series		No Opt. Call		BBB+		1,071,490
		2002, 4.600%, 11/15/12
1,380		North Little Rock, Arkansas, Electric Revenue Refunding Bonds, Series 1992A, 6.500%, 7/01/15 –		No Opt. Call		AA–		1,537,886
		MBIA Insured
4,880		Total Arkansas						5,183,561
		California – 1.1%
400		California Health Facilities Financing Authority, Revenue Bonds, Catholic Healthcare West,		7/15 at 100.00		A		394,144
		Series 2008H, 5.125%, 7/01/22
255		Golden State Tobacco Securitization Corporation, California, Enhanced Tobacco Settlement		6/17 at 100.00		BBB		211,867
		Asset-Backed Bonds, Series 2007A-1, 4.500%, 6/01/27
2,000		Palomar Pomerado Health, California, General Obligation Bonds, Election of 2004, Series 2009A,		No Opt. Call		AAA		735,080
		0.000%, 8/01/25 – AGC Insured
2,655		Total California						1,341,091
		Colorado – 12.8%
2,895		Centennial Downs Metropolitan District, Colorado, General Obligation Bonds, Series 1999,		12/14 at 100.00		BBB		3,033,265
		5.000%, 12/01/20 – AMBAC Insured
1,200		Colorado Educational and Cultural Facilities Authority, Charter School Revenue Bonds, Douglas		7/12 at 100.00		BBB		1,076,184
		County School District RE-1 – DCS Montessori School, Series 2002A, 6.000%, 7/15/22
1,175		Colorado Educational and Cultural Facilities Authority, Revenue Bonds, Classical Academy		12/13 at 100.00		A		1,056,337
		Charter School, Series 2003, 4.500%, 12/01/18 – SYNCORA GTY Insured
265		Colorado Housing Finance Authority, Single Family Program Senior Bonds, Series 2000D-2,		4/10 at 105.00		AA		279,403
		6.900%, 4/01/29 (Alternative Minimum Tax)
1,025		Denver Health and Hospitals Authority, Colorado, Healthcare Revenue Bonds, Series 2001A,		12/11 at 100.00		N/R (4)		1,133,353
		6.000%, 12/01/23 (Pre-refunded 12/01/11)
1,465		Denver West Metropolitan District, Colorado, General Obligation Refunding and Improvement		12/13 at 100.00		BBB–		1,244,298
		Bonds, Series 2003, 4.500%, 12/01/18 – RAAI Insured
1,500		E-470 Public Highway Authority, Colorado, Senior Revenue Bonds, Series 2007C-2, 5.000%,		No Opt. Call		A		1,505,100
		9/01/39 (Mandatory put 9/01/13) – MBIA Insured
1,000		E-470 Public Highway Authority, Colorado, Toll Revenue Bonds, Series 2004B, 0.000%, 3/01/36 –		No Opt. Call		A		121,960
		MBIA Insured
15		El Paso County, Colorado, FNMA Mortgage-Backed Single Family Revenue Refunding Bonds, Series		No Opt. Call		Aaa		16,079
		1992A-2, 8.750%, 6/01/11
1,050		Erie, Boulder and Weld Counties, Colorado, Water Enterprise Revenue Bonds, Series 1998,		9/09 at 100.00		N/R		776,328
		5.000%, 12/01/23 – ACA Insured
70		Northwest Parkway Public Highway Authority, Colorado, Revenue Bonds, Senior Series 2001A,		6/11 at 102.00		AAA		76,435
		5.250%, 6/15/41 (Pre-refunded 6/15/11) – FSA Insured
5,875		Northwest Parkway Public Highway Authority, Colorado, Senior Lien Revenue Bonds, Series 2001B,		6/11 at 38.04		N/R (4)		2,154,480
		0.000%, 6/15/27 (Pre-refunded 6/15/11) – AMBAC Insured
2,845		University of Colorado Hospital Authority, Revenue Bonds, Series 2001A, 5.600%, 11/15/21		11/11 at 100.00		A3 (4)		3,124,863
		(Pre-refunded 11/15/11)
20,380		Total Colorado						15,598,085
		Connecticut – 1.6%
		Eastern Connecticut Resource Recovery Authority, Solid Waste Revenue Bonds, Wheelabrator
		Lisbon Project, Series 1993A:
395		5.500%, 1/01/14 (Alternative Minimum Tax)		9/09 at 100.00		BBB		388,143
1,570		5.500%, 1/01/15 (Alternative Minimum Tax)		9/09 at 100.00		BBB		1,534,016
1,965		Total Connecticut						1,922,159
		Florida – 5.7%
2,400		Deltona, Florida, Utility Systems Water and Sewer Revenue Bonds, Series 2003, 5.250%, 10/01/17 –		10/13 at 100.00		A		2,418,600
		MBIA Insured
1,000		Florida Citizens Property Insurance Corporation, High Risk Account Revenue Bonds, Series		No Opt. Call		A+		993,940
		2007A, 5.000%, 3/01/15 – MBIA Insured
600		Florida Deparmtent of Environmental Protection, Florida Forever Revenue Bonds, Series 2007B,		7/17 at 101.00		AA–		615,528
		5.000%, 7/01/19 – MBIA Insured
45		JEA, Florida, Electric Revenue Certificates, Series 1973-2, 6.800%, 7/01/12 (ETM)		No Opt. Call		AAA		48,630
2,000		Orange County, Florida, Tourist Development Tax Revenue Bonds, Series 2005, 5.000%, 10/01/22 –		10/15 at 100.00		A+		2,016,620
		AMBAC Insured
295		Port Everglades Authority, Florida, Port Facilities Revenue Bonds, Series 1986, 7.125%,		No Opt. Call		AAA		345,740
		11/01/16 (ETM)
500		South Miami Health Facilities Authority, Florida, Hospital Revenue, Baptist Health System		8/17 at 100.00		AA–		480,945
		Obligation Group, Series 2007, 5.000%, 8/15/27
6,840		Total Florida						6,920,003
		Georgia – 0.4%
425		Cherokee County Water and Sewerage Authority, Georgia, Revenue Bonds, Series 1995, 5.200%,		8/22 at 100.00		A (4)		472,286
		8/01/25 (Pre-refunded 8/01/22) – MBIA Insured
		Idaho – 0.1%
100		Madison County, Idaho, Hospital Revenue Certificates of Participation, Madison Memorial		9/16 at 100.00		BBB–		72,313
		Hospital, Series 2006, 5.250%, 9/01/37
		Illinois – 14.8%
635		Chicago, Illinois, Tax Increment Allocation Bonds, Irving/Cicero Redevelopment Project, Series		7/09 at 100.00		N/R		634,397
		1998, 7.000%, 1/01/14
1,500		Cook County Township High School District 208, Illinois, General Obligation Bonds, Series		12/15 at 100.00		A1		1,570,815
		2006, 5.000%, 12/01/21 – MBIA Insured
2,000		Huntley, Illinois, Special Service Area 9, Special Tax Bonds, Series 2007, 5.100%, 3/01/28 –		3/17 at 100.00		AAA		1,990,320
		AGC Insured
4,820		Illinois Development Finance Authority, GNMA Collateralized Mortgage Revenue Bonds, Greek		4/11 at 105.00		Aaa		5,475,131
		American Nursing Home Committee, Series 2000A, 7.600%, 4/20/40
2,000		Illinois Development Finance Authority, Revenue Refunding Bonds, Olin Corporation, Series		4/10 at 102.00		Baa3		1,860,220
		1993D, 6.750%, 3/01/16
2,000		Illinois Educational Facilities Authority, Revenue Bonds, Art Institute of Chicago, Series		3/14 at 102.00		N/R		2,104,320
		2000, 4.450%, 3/01/34 (Mandatory put 3/01/15)
1,000		Illinois Educational Facilities Authority, Student Housing Revenue Bonds, Educational Advancement		5/12 at 101.00		Aaa		1,156,050
		Foundation Fund, University Center Project, Series 2002, 6.625%, 5/01/17 (Pre-refunded 5/01/12)
250		Illinois Finance Authority, Revenue Bonds, Roosevelt University, Series 2007, 5.250%, 4/01/22		4/17 at 100.00		Baa1		231,120
25		Illinois Health Facilities Authority, Revenue Bonds, Condell Medical Center, Series 2000,		5/10 at 101.00		Aaa		26,503
		6.350%, 5/15/15 (Pre-refunded 5/15/10)
20		Illinois Health Facilities Authority, Revenue Bonds, Condell Medical Center, Series 2002,		No Opt. Call		Baa3 (4)		22,123
		5.250%, 5/15/12 (ETM)
70		Illinois Health Facilities Authority, Revenue Bonds, Lutheran General Health System, Series		No Opt. Call		AAA		75,075
		1993A, 6.125%, 4/01/12 – FSA Insured (ETM)
695		Illinois Health Facilities Authority, Revenue Bonds, Silver Cross Hospital and Medical		8/09 at 101.00		BBB		661,272
		Centers, Series 1999, 5.500%, 8/15/19
515		Illinois Health Facilities Authority, Revenue Bonds, Silver Cross Hospital and Medical		8/09 at 101.00		BBB (4)		523,219
		Centers, Series 1999, 5.500%, 8/15/19 (Pre-refunded 8/15/09)
1,355		Kane & DeKalb Counties, Illinois, Community United School District 301, General Obligation		No Opt. Call		A3		886,035
		Bonds, Series 2006, 0.000%, 12/01/18 – MBIA Insured
700		Regional Transportation Authority, Cook, DuPage, Kane, Lake, McHenry and Will Counties,		No Opt. Call		AA+		876,421
		Illinois, General Obligation Bonds, Series 1994D, 7.750%, 6/01/19 – FGIC Insured
17,585		Total Illinois						18,093,021
		Indiana – 0.2%
250		Jasper County, Indiana, Pollution Control Revenue Refunding Bonds, Northern Indiana Public		No Opt. Call		AA		249,148
		Service Company Project, Series 1994A Remarketed, 5.850%, 4/01/19 – MBIA Insured
		Iowa – 2.3%
1,000		Iowa Finance Authority, Healthcare Revenue Bonds, Genesis Medical Center, Series 2000,		7/10 at 100.00		A1		1,001,630
		6.250%, 7/01/25
1,725		Iowa Tobacco Settlement Authority, Tobacco Settlement Asset-Backed Revenue Bonds, Series		6/11 at 101.00		AAA		1,847,906
		2001B, 5.300%, 6/01/25 (Pre-refunded 6/01/11)
2,725		Total Iowa						2,849,536
		Kansas – 3.1%
3,500		Wichita, Kansas, Hospital Facilities Revenue Refunding and Improvement Bonds, Via Christi		11/11 at 101.00		A+		3,512,668
		Health System Inc., Series 2001-III, 5.500%, 11/15/21
250		Wyandotte County-Kansas City Unified Government, Kansas, Sales Tax Special Obligation Bonds,		12/15 at 100.00		N/R		234,848
		Redevelopment Project Area B, Series 2005, 5.000%, 12/01/20
3,750		Total Kansas						3,747,516
		Kentucky – 1.2%
325		Kentucky Economic Development Finance Authority, Louisville Arena Project Revenue Bonds,		6/18 at 100.00		AAA		336,206
		Louisville Arena Authority, Inc., Series 2008A-1, 5.750%, 12/01/28 – AGC Insured
1,205		Kentucky Housing Corporation, Housing Revenue Bonds, Series 2005G, 5.000%, 7/01/30		1/15 at 100.60		AAA		1,142,714
		(Alternative Minimum Tax)
1,530		Total Kentucky						1,478,920
		Louisiana – 1.2%
1,010		Louisiana Public Facilities Authority, Revenue Bonds, Baton Rouge General Hospital, Series		7/14 at 100.00		A		1,025,514
		2004, 5.250%, 7/01/24 – MBIA Insured
		Tobacco Settlement Financing Corporation, Louisiana, Tobacco Settlement Asset-Backed Bonds,
		Series 2001B:
300		5.500%, 5/15/30		5/11 at 101.00		BBB		288,744
200		5.875%, 5/15/39		5/11 at 101.00		BBB		157,538
1,510		Total Louisiana						1,471,796
		Maryland – 0.8%
1,100		Maryland Energy Financing Administration, Revenue Bonds, AES Warrior Run Project, Series 1995,		9/09 at 100.00		N/R		988,515
		7.400%, 9/01/19 (Alternative Minimum Tax)
		Massachusetts – 1.7%
500		Massachusetts Development Finance Agency, Revenue Bonds, Orchard Cove, Series 2007,		10/17 at 100.00		N/R		377,920
		5.000%, 10/01/19
1,445		Massachusetts Housing Finance Agency, Rental Housing Mortgage Revenue Bonds, Series 2000H,		7/10 at 100.00		A		1,457,254
		6.650%, 7/01/41 – MBIA Insured (Alternative Minimum Tax)
		Massachusetts Port Authority, Special Facilities Revenue Bonds, Delta Air Lines Inc., Series 2001A:
100		5.200%, 1/01/20 – AMBAC Insured (Alternative Minimum Tax)		1/11 at 101.00		BBB		64,813
435		5.000%, 1/01/27 – AMBAC Insured (Alternative Minimum Tax)		1/11 at 101.00		BBB		232,934
2,480		Total Massachusetts						2,132,921
		Michigan – 1.7%
1,000		Cornell Township Economic Development Corporation, Michigan, Environmental Improvement Revenue		5/12 at 100.00		AAA		1,117,010
		Refunding Bonds, MeadWestvaco Corporation-Escanaba Project, Series 2002, 5.875%, 5/01/18
		(Pre-refunded 5/01/12)
525		Michigan State Hospital Finance Authority, Hospital Revenue Refunding Bonds, Sinai Hospital,		7/09 at 100.00		BB		473,051
		Series 1995, 6.625%, 1/01/16
470		Michigan State Hospital Finance Authority, Revenue Refunding Bonds, Detroit Medical Center,		9/09 at 100.00		BB–		469,676
		Series 1988A, 8.125%, 8/15/12
1,995		Total Michigan						2,059,737
		Minnesota – 1.8%
1,100		Becker, Minnesota, Pollution Control Revenue Bonds, Northern States Power Company, Series		8/12 at 101.00		A		1,237,995
		1993A, 8.500%, 9/01/19
250		Northern Municipal Power Agency, Minnesota, Electric System Revenue Bonds, Refunding Series		No Opt. Call		AAA		268,753
		2009A, 5.000%, 1/01/15 – AGC Insured
640		White Earth Band of Chippewa Indians, Minnesota, Revenue Bonds, Series 2000A, 7.000%, 12/01/11 –		No Opt. Call		N/R		660,806
		ACA Insured
1,990		Total Minnesota						2,167,554
		Mississippi – 0.8%
		Mississippi Hospital Equipment and Facilities Authority, Revenue Bonds, Baptist Memorial
		Healthcare, Series 2004B-1:
485		5.000%, 9/01/16		No Opt. Call		AA		502,538
300		5.000%, 9/01/24		9/14 at 100.00		AA		299,664
250		Warren County, Mississippi, Gulf Opportunity Zone Revenue Bonds, International Paper Company,		8/11 at 100.00		BBB		182,075
		Series 2006A, 4.800%, 8/01/30
1,035		Total Mississippi						984,277
		Montana – 0.1%
60		University of Montana, Revenue Bonds, Series 1996D, 5.375%, 5/15/19 – MBIA Insured (ETM)		9/09 at 100.00		A (4)		68,638
		Nebraska – 0.9%
1,000		Dodge County School District 1, Nebraska, Fremont Public Schools, General Obligation Bonds,		12/14 at 100.00		Aa3		1,059,090
		Series 2004, 5.000%, 12/15/19 – FSA Insured
30		NebHelp Inc., Nebraska, Senior Subordinate Bonds, Student Loan Program, Series 1993A-5B,		No Opt. Call		Aa2		31,406
		6.250%, 6/01/18 – MBIA Insured (Alternative Minimum Tax)
1,030		Total Nebraska						1,090,496
		Nevada – 0.4%
		Director of Nevada State Department of Business and Industry, Revenue Bonds, Las Vegas
		Monorail Project, First Tier, Series 2000:
800		0.000%, 1/01/15 – AMBAC Insured		No Opt. Call		Caa2		188,296
35		0.000%, 1/01/16 – AMBAC Insured		No Opt. Call		Caa2		7,501
120		0.000%, 1/01/18 – AMBAC Insured		No Opt. Call		Caa2		21,953
50		0.000%, 1/01/20 – AMBAC Insured		No Opt. Call		Caa2		8,104
250		Las Vegas Redevelopment Agency, Nevada, Tax Increment Revenue Bonds, Series 2009A,		6/19 at 100.00		A		262,943
		8.000%, 6/15/30
1,255		Total Nevada						488,797
		New Jersey – 0.5%
455		Bayonne Redevelopment Agency, New Jersey, Revenue Bonds, Royal Caribbean Cruises Project,		No Opt. Call		BB–		277,828
		Series 2006A, 4.750%, 11/01/16 (Alternative Minimum Tax)
445		Tobacco Settlement Financing Corporation, New Jersey, Tobacco Settlement Asset-Backed Bonds,		6/17 at 100.00		BBB		376,599
		Series 2007-1A, 4.500%, 6/01/23
900		Total New Jersey						654,427
		New York – 6.1%
1,000		Dormitory Authority of the State of New York, Revenue Bonds, Brooklyn Law School, Series		7/13 at 100.00		BBB+		1,037,370
		2003A, 5.500%, 7/01/15 – RAAI Insured
240		New York City Industrial Development Agency, New York, Civic Facility Revenue Bonds, Special		No Opt. Call		N/R		220,056
		Needs Facilities Pooled Program, Series 2008A-1, 5.700%, 7/01/13
1,500		New York State Energy Research and Development Authority, Facilities Revenue Bonds, Consolidated		9/09 at 100.00		A		1,500,435
		Edison Company Inc., Series 2001A, 4.700%, 6/01/36 (Mandatory put 10/01/12) (Alternative
		Minimum Tax)
145		New York State Tobacco Settlement Financing Corporation, Tobacco Settlement Asset-Backed and		6/13 at 100.00		AA–		146,644
		State Contingency Contract-Backed Bonds, Series 2003A-1, 5.250%, 6/01/20 – AMBAC Insured
4,300		Port Authority of New York and New Jersey, Special Project Bonds, JFK International Air		No Opt. Call		A		4,506,484
		Terminal LLC, Sixth Series 1997, 7.000%, 12/01/12 – MBIA Insured (Alternative Minimum Tax)
7,185		Total New York						7,410,989
		North Carolina – 1.6%
1,880		Union County, North Carolina, Certificates of Participation, Series 2003, 5.000%, 6/01/18 –		6/13 at 101.00		AA–		1,966,405
		AMBAC Insured
		Ohio – 1.4%
775		Buckeye Tobacco Settlement Financing Authority, Ohio, Tobacco Settlement Asset-Backed Revenue		6/17 at 100.00		BBB		626,301
		Bonds, Senior Lien, Series 2007A-2, 5.125%, 6/01/24
1,000		Toledo-Lucas County Port Authority, Ohio, Port Revenue Bonds, Cargill Inc., Series 2004B,		No Opt. Call		A		1,034,900
		4.500%, 12/01/15
1,775		Total Ohio						1,661,201
		Pennsylvania – 7.4%
400		Pennsylvania Economic Development Financing Authority, Pollution Control Revenue Bonds, PPL		No Opt. Call		A–		406,256
		Electric Utilities Corporation, Refunding Series 2008, 4.850%, 10/01/23 (Mandatory put 10/01/10)
895		Pennsylvania Higher Educational Facilities Authority, College Revenue Bonds, Ninth Series		No Opt. Call		Aaa		1,035,103
		1976, 7.625%, 7/01/15 (ETM)
225		Pennsylvania Higher Educational Facilities Authority, Revenue Bonds, University of the Arts,		9/09 at 100.00		BBB– (4)		233,658
		Series 1999, 5.150%, 3/15/20 – RAAI Insured (ETM)
4,120		Philadelphia Gas Works, Pennsylvania, Revenue Bonds, Eighteenth Series 2004, 5.000%, 8/01/15 –		8/14 at 100.00		BBB		4,094,866
		AMBAC Insured
1,535		Philadelphia Gas Works, Pennsylvania, Revenue Bonds, Twelfth Series 1990B, 7.000%, 5/15/20 –		No Opt. Call		Aaa		1,878,103
		MBIA Insured (ETM)
250		Philadelphia Hospitals and Higher Education Facilities Authority, Pennsylvania, Hospital		9/09 at 100.00		BBB		242,663
		Revenue Bonds, Temple University Hospital, Series 1993A, 6.625%, 11/15/23
1,085		Pittsburgh School District, Allegheny County, Pennsylvania, General Obligation Bonds, Series		No Opt. Call		A1		1,169,532
		2006B, 5.000%, 9/01/12 – AMBAC Insured
8,510		Total Pennsylvania						9,060,181
		Puerto Rico – 0.5%
1,000		Puerto Rico Sales Tax Financing Corporation, Sales Tax Revenue Bonds, First Subordinate Series		8/26 at 100.00		A+		631,000
		2009A, 0.000%, 8/01/32
		Rhode Island – 0.5%
		Rhode Island Tobacco Settlement Financing Corporation, Tobacco Settlement Asset-Backed Bonds,
		Series 2002A:
110		6.125%, 6/01/32		6/12 at 100.00		BBB		90,965
670		6.250%, 6/01/42		6/12 at 100.00		BBB		520,081
780		Total Rhode Island						611,046
		South Carolina – 6.0%
750		Berkeley County School District, South Carolina, Installment Purchase Revenue Bonds, Securing		12/13 at 100.00		A–		766,530
		Assets for Education, Series 2003, 5.250%, 12/01/19
1,540		Piedmont Municipal Power Agency, South Carolina, Electric Revenue Bonds, Series 1991, 6.750%,		No Opt. Call		Baa1 (4)		1,988,587
		1/01/19 – FGIC Insured (ETM)
2,835		Piedmont Municipal Power Agency, South Carolina, Electric Revenue Bonds, Series 1991, 6.750%,		No Opt. Call		Baa1		3,273,487
		1/01/19 – FGIC Insured
5		South Carolina JOBS Economic Development Authority, Economic Development Revenue Bonds, Bon		11/12 at 100.00		A3 (4)		5,683
		Secours Health System Inc., Series 2002A, 5.625%, 11/15/30 (Pre-refunded 11/15/12)
20		South Carolina JOBS Economic Development Authority, Economic Development Revenue Bonds, Bon		11/12 at 100.00		A–		18,513
		Secours Health System Inc., Series 2002B, 5.625%, 11/15/30
865		South Carolina JOBS Economic Development Authority, Hospital Revenue Bonds, Palmetto Health		No Opt. Call		Baa2 (4)		909,842
		Alliance, Series 2000A, 7.000%, 12/15/10 (ETM)
325		Tobacco Settlement Revenue Management Authority, South Carolina, Tobacco Settlement		5/11 at 101.00		BBB (4)		342,602
		Asset-Backed Bonds, Series 2001B, 6.000%, 5/15/22 (Pre-refunded 5/15/11)
6,340		Total South Carolina						7,305,244
		South Dakota – 0.8%
1,000		South Dakota Health and Educational Facilities Authority, Revenue Bonds, Sanford Health,		5/17 at 100.00		AA–		937,140
		Series 2007, 5.000%, 11/01/27
		Tennessee – 2.2%
		Shelby County Health, Educational and Housing Facilities Board, Tennessee, Hospital Revenue
		Bonds, Methodist Healthcare, Series 2002:
750		6.000%, 9/01/17 (Pre-refunded 9/01/12)		9/12 at 100.00		N/R (4)		851,198
1,250		6.000%, 9/01/17 (Pre-refunded 9/01/12)		9/12 at 100.00		N/R (4)		1,418,663
400		The Tennessee Energy Acquisition Corporation, Gas Revenue Bonds, Series 2006A, 5.000%, 9/01/13		No Opt. Call		BBB		395,284
2,400		Total Tennessee						2,665,145
		Texas – 6.6%
1,055		Austin, Texas, General Obligation Bonds, Series 2004, 5.000%, 9/01/20 – MBIA Insured		9/14 at 100.00		AAA		1,103,266
565		Bexar County Housing Finance Corporation, Texas, FNMA Guaranteed Multifamily Housing Revenue		No Opt. Call		AAA		579,984
		Bonds, Villas Sonterra Apartments Project, Series 2007A, 4.700%, 10/01/15 (Alternative
		Minimum Tax)
25		Brazos River Authority, Texas, Collateralized Pollution Control Revenue Bonds, Texas Utilities		No Opt. Call		CCC		13,866
		Electric Company, Series 2003D, 5.400%, 10/01/29 (Mandatory put 10/01/14)
2,000		Brazos River Authority, Texas, Collateralized Revenue Refunding Bonds, CenterPoint Energy		6/14 at 100.00		BBB+		1,798,060
		Inc., Series 2004B, 4.250%, 12/01/17 – FGIC Insured
500		Brazos River Authority, Texas, Pollution Control Revenue Refunding Bonds, TXU Electric		No Opt. Call		CCC		384,330
		Company, Series 2001C, 5.750%, 5/01/36 (Mandatory put 11/01/11) (Alternative Minimum Tax)
15		Brazos River Authority, Texas, Pollution Control Revenue Refunding Bonds, TXU Energy Company		No Opt. Call		CCC		9,696
		LLC, Series 2003A, 6.750%, 4/01/38 (Mandatory put 4/01/13) (Alternative Minimum Tax)
1,875		Denton Independent School District, Denton County, Texas, General Obligation Bonds, Series		8/16 at 100.00		AAA		2,031,244
		2006, 5.000%, 8/15/20
20		Galveston Property Finance Authority Inc., Texas, Single Family Mortgage Revenue Bonds, Series		9/09 at 100.00		Caa1		19,698
		1991A, 8.500%, 9/01/11
300		Kerrville Health Facilities Development Corporation, Texas, Revenue Bonds, Sid Peterson		No Opt. Call		BBB–		256,629
		Memorial Hospital Project, Series 2005, 5.125%, 8/15/26
325		North Texas Thruway Authority, Second Tier System Revenue Refunding Bonds, Series 2008,		1/18 at 100.00		A3		312,683
		5.750%, 1/01/38
25		Sabine River Authority, Texas, Pollution Control Revenue Bonds, TXU Energy Company LLC		No Opt. Call		CCC		19,217
		Project, Series 2001B, 5.750%, 5/01/30 (Mandatory put 11/01/11) (Alternative Minimum Tax)
1,500		Texas Municipal Gas Acquisition and Supply Corporation I, Gas Supply Revenue Bonds, Series		9/09 at 100.00		A		1,126,500
		2006B, 1.887%, 12/15/17
270		Tri-County Mental Health and Retardation Center, Texas, Revenue Bonds, Facilities Acquisition		9/09 at 100.00		AAA		271,909
		Program, Series 1995E, 6.500%, 3/01/15 – FSA Insured
160		Weslaco Health Facilities Development Corporation, Texas, Hospital Revenue Bonds, Knapp		6/12 at 100.00		BBB+ (4)		172,758
		Medical Center, Series 2002, 6.000%, 6/01/17 (Pre-refunded 6/01/12)
8,635		Total Texas						8,099,840
		Utah – 0.5%
680		Bountiful, Davis County, Utah, Hospital Revenue Refunding Bonds, South Davis Community		No Opt. Call		N/R		667,175
		Hospital Project, Series 1998, 6.000%, 12/15/10
		Virginia – 0.2%
250		Virginia College Building Authority, Educational Facilities Revenue Refunding Bonds, Marymount		7/09 at 100.50		BBB–		237,693
		University, Series 1998, 5.100%, 7/01/18 – RAAI Insured
		Washington – 0.3%
295		Washington Public Power Supply System, Revenue Refunding Bonds, Nuclear Project 3, Series		No Opt. Call		Aaa		366,290
		1989B, 7.125%, 7/01/16 – MBIA Insured
25		Washington State Tobacco Settlement Authority, Tobacco Settlement Asset-Backed Revenue Bonds,		6/13 at 100.00		BBB		24,796
		Series 2002, 6.500%, 6/01/26
320		Total Washington						391,086
		Wisconsin – 3.9%
		Badger Tobacco Asset Securitization Corporation, Wisconsin, Tobacco Settlement Asset-Backed
		Bonds, Series 2002:
570		6.125%, 6/01/27 (Pre-refunded 6/01/12)		6/12 at 100.00		AAA		619,619
1,480		6.375%, 6/01/32 (Pre-refunded 6/01/12)		6/12 at 100.00		AAA		1,656,668
1,000		Wisconsin Health and Educational Facilities Authority, Revenue Bonds, Agnesian Healthcare		7/11 at 100.00		A–		1,012,000
		Inc., Series 2001, 6.000%, 7/01/21
1,150		Wisconsin Health and Educational Facilities Authority, Revenue Bonds, Aurora Health Care Inc.,		2/10 at 100.00		BBB+		1,111,337
		Series 1999A, 5.500%, 2/15/20 – ACA Insured
		Wisconsin Health and Educational Facilities Authority, Revenue Bonds, Wheaton Franciscan
		Healthcare System, Series 2006:
200		5.250%, 8/15/18		8/16 at 100.00		BBB+		184,272
180		5.250%, 8/15/34		8/16 at 100.00		BBB+		134,312
4,580		Total Wisconsin						4,718,208
$     126,205		Total Investments (cost $121,414,876) – 98.7%						120,447,377
		Other Assets Less Liabilities – 1.3%						1,541,940
		Net Assets – 100%					$	121,989,317

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Fair Value Measurements

In determining the value of the Fund’s investments various inputs are used. These inputs are summarized in the three broad levels listed below:

Level 1 – Quoted prices in active markets for identical securities.

Level 2 – Other significant observable inputs (including quoted prices for similar securities, interest rates, prepayment speeds, credit risk, etc.).

Level 3 – Significant unobservable inputs (including management’s assumptions in determining the fair value of investments).

The inputs or methodology used for valuing securities are not an indication of the risk associated with investing in those securities. The following is a summary of the Fund’s fair value measurements as of June 30, 2009:

		Level 1		Level 2		Level 3		Total
Investments:
Municipal Bonds		$ —		$120,447,377		$ —		$120,447,377

Income Tax Information

The following information is presented on an income tax basis. Differences between amounts for financial statement and federal income tax purposes are primarily due to timing differences in recognizing taxable market discount, timing differences in recognizing certain gains and losses on investment transactions and the treatment of investments in inverse floating rate transactions subject to Statement of Financial Accounting Standards No. 140 (SFAS No. 140), if any. To the extent that differences arise that are permanent in nature, such amounts are reclassified within the capital accounts on the Statement of Assets and Liabilities presented in the annual report, based on their federal tax basis treatment; temporary differences do not require reclassification. Temporary and permanent differences do not impact the net asset value of the Fund.

At June 30, 2009, the cost of investments was $121,336,086.

Gross unrealized appreciation and gross unrealized depreciation of investments at June 30, 2009, were as follows:

Gross unrealized:
Appreciation		$ 3,578,631
Depreciation		(4,467,340)
Net unrealized appreciation (depreciation) of investments		$  (888,709)

(1)		All percentages shown in the Portfolio of Investments are based on net assets.
(2)		Optional Call Provisions: Dates (month and year) and prices of the earliest optional call or redemption.
		There may be other call provisions at varying prices at later dates. Certain mortgage-backed securities
		may be subject to periodic principal paydowns.
(3)		Ratings: Using the higher of Standard & Poor’s Group (“Standard & Poor’s”) or Moody’s Investor Service,
		Inc. (“Moody’s”) rating. Ratings below BBB by Standard & Poor’s or Baa by Moody’s are considered to be
		below investment grade.
(4)		Backed by an escrow or trust containing sufficient U.S. Government or U.S. Government agency securities
		which ensure the timely payment of principal and interest. Such investments are normally considered to
		be equivalent to AAA rated securities.
N/R		Not rated.
(ETM)		Escrowed to maturity.

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Item 2. Controls and Procedures.

1. The registrant's principal executive and principal financial officers, or persons performing similar functions, have concluded that the registrant's disclosure controls and procedures (as defined in Rule 30a-3(c) under the Investment Company Act of 1940, as amended (the "1940 Act") (17 CFR 270.30a-3(c))) are effective, as of a date within 90 days of the filing date of this report that includes the disclosure required by this paragraph, based on their evaluation of the controls and procedures required by Rule 30a-3(b) under the 1940 Act (17 CFR 270.30a-3(b)) and Rule 13a-15(b) or 15d-15(b) under the Securities Exchange Act of 1934 (17 CFR 240.13a-15(b) or 240.15d-15(b)).
2. There were no changes in the registrant's internal control over financial reporting (as defined in Rule 30a-3(d) under the 1940 Act (17 CFR 270.30a-3(d)) that occurred during the registrant's last fiscal quarter that have materially affected, or are reasonably likely to materially affect, the registrant's internal control over financial reporting.

Item 3. Exhibits.

File as exhibits as part of this Form a separate certification for each principal executive officer and principal financial officer of the registrant as required by Rule 30a-2(a) under the 1940 Act (17 CFR 270.30a-2(a)), exactly as set forth below: See EX-99 CERT attached hereto.

SIGNATURES

Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, the registrant has duly caused this report to be signed on its behalf by the undersigned, thereunto duly authorized.

(Registrant)         Nuveen Select Maturities Municipal Fund         

By (Signature and Title)          /s/ Kevin J. McCarthy                    
                                                  Kevin J. McCarthy
                                                  Vice President and Secretary

Date         August 28, 2009        

Pursuant to the requirements of the Securities Exchange Act of 1934 and the Investment Company Act of 1940, this report has been signed below by the following persons on behalf of the registrant and in the capacities and on the dates indicated.

By (Signature and Title)         /s/ Gifford R. Zimmerman                    
                                                 Gifford R. Zimmerman
                                                 Chief Administrative Officer (principal executive officer) 

Date         August 28, 2009        

By (Signature and Title)         /s/ Stephen D. Foy                              
                                                 Stephen D. Foy
                                                 Vice President and Controller (principal financial officer) 

Date        August 28, 2009